Self-Healing Layer Significantly Boosts the Safety and Lifespan of All-Solid-State Lithium Batteries

Self-healing layer for solid-state batteries

A research team from the Chinese Academy of Sciences has developed a novel self-healing layer that dramatically improves the safety, stability, and lifespan of all-solid-state lithium metal batteries (ASSLMBs). These next-generation energy storage systems are widely considered the future of electric vehicles and renewable energy grids thanks to their higher energy density and intrinsic safety compared to conventional lithium-ion batteries.

The key innovation, published in Nature Sustainability in October 2025, involves the creation of a Dynamically Adaptive Interphase (DAI) layer that can autonomously repair internal gaps that typically form during battery cycling. This self-healing mechanism addresses one of the most critical obstacles preventing the large-scale adoption of ASSLMBs.

Why All-Solid-State Batteries Are Promising — and Problematic

Conventional lithium-ion batteries rely on flammable liquid electrolytes to conduct ions between the cathode and anode. This design, while effective, introduces risks of leakage, fire, and thermal runaway. All-solid-state lithium metal batteries replace the liquid with non-flammable solid electrolytes, improving safety and offering the potential for much higher energy densities — enabling electric vehicles with longer ranges and safer grid storage systems.

However, a persistent problem has limited their reliability: during repeated charging and discharging cycles, voids and gaps form at the interface between the solid lithium metal anode and the solid electrolyte. These gaps disrupt ion transport, leading to rapid capacity loss, instability, and eventual battery failure. Current workarounds involve applying high external pressure to keep the layers in contact — a method that is impractical and expensive for commercial applications.

The Self-Healing “DAI” Layer: A Dynamic Solution

The research team tackled this issue by introducing a special layer called the Dynamically Adaptive Interphase (DAI) between the lithium anode and the solid electrolyte. This layer contains mobile iodide ions that migrate under the influence of the battery’s electric field to fill any newly formed voids during cycling. In effect, the DAI acts as a self-healing seal, maintaining continuous interfacial contact without the need for external pressure.

This innovation represents a **paradigm shift in solid-state battery design**, as it combines high ionic conductivity with adaptive interface stability — two properties that are typically difficult to achieve simultaneously.

Exceptional Performance Results

The DAI-equipped solid-state batteries showed **remarkable cycling stability**. Laboratory tests demonstrated that full cells retained **over 90% of their energy capacity after 2,400 charge–discharge cycles** — a performance far superior to typical solid-state designs.

The researchers also tested a **pouch cell**, a common battery format for consumer electronics and electric vehicles, and found that it maintained **74.4% of its capacity after 300 cycles without applying any external pressure**. This shows the DAI layer can enable practical battery assemblies without the need for bulky, energy-inefficient compression systems.

Implications for the Future of Energy Storage

The introduction of self-healing interphases could **accelerate the commercialization of solid-state batteries**, enabling safer electric vehicles with longer driving ranges, as well as **durable, maintenance-free grid storage** for renewable energy. The pressure-free design also simplifies manufacturing, potentially reducing production costs and scaling barriers.

As the researchers note, the DAI strategy “represents a paradigm shift in solid-state battery design, accelerating the practical implementation of high-energy and sustainable electrochemical storage systems in current energy networks.”

Original article: Self-healing layer improves the safety and lifespan of all-solid-state lithium batteries (TechXplore, October 13, 2025) .

This blog article for Quantum Server Networks was prepared with the help of AI technologies.

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