Magnesium Battery Breakthrough: Prototype Achieves Stable Operation at Room Temperature

Rechargeable magnesium battery prototype

As the global demand for sustainable and large-scale energy storage continues to rise, researchers are searching for alternatives to lithium-ion technology that are both more abundant and more stable. In a major step forward, scientists at Tohoku University have unveiled a prototype rechargeable magnesium battery (RMB) that operates stably at room temperature — a feat that has eluded researchers for decades. Their findings, published in Communications Materials, mark a pivotal advance in the development of next-generation batteries.

This breakthrough suggests that magnesium batteries could become a viable, sustainable, and fast-charging alternative to lithium-based systems. Given the global scarcity of lithium and the increasing pressure on supply chains, magnesium’s abundance in the Earth's crust makes it an attractive candidate for scalable battery technologies.

Why Magnesium? A Sustainable Alternative to Lithium

Lithium-ion batteries currently dominate portable electronics, electric vehicles, and renewable energy storage. However, lithium is a relatively scarce resource, concentrated in a few geographic regions, and its extraction raises environmental concerns. Magnesium, by contrast, is widely available and less expensive. It also offers the theoretical advantage of higher volumetric energy density due to its divalent nature (Mg²⁺), meaning more charge can be stored per ion compared to lithium.

Despite these advantages, magnesium batteries have long been held back by a major obstacle: sluggish Mg-ion diffusion at room temperature. Previous systems required elevated temperatures to operate, making them impractical for real-world use.

Amorphous Oxide Cathode Enables Room-Temperature Operation

The Tohoku University team, led by Tetsu Ichitsubo, overcame this bottleneck by designing a novel amorphous oxide cathode with the composition Mg0.27Li0.09Ti0.11Mo0.22O. This material enables rapid Mg-ion transport through an ion-exchange mechanism between lithium and magnesium, effectively creating structural pathways that allow Mg²⁺ ions to move easily — even at room temperature.

Using this cathode, the researchers built a prototype coin-cell magnesium battery that successfully powered a blue light-emitting diode (LED), demonstrating output voltages exceeding 2.5 V. Even after 200 charge–discharge cycles, the cell maintained stable energy output under ambient conditions — a significant improvement over previous magnesium battery attempts, which often showed negative discharge voltages or rapid degradation.

Laying the Groundwork for Next-Generation Batteries

Detailed chemical analysis confirmed that the observed capacity comes from true magnesium intercalation rather than parasitic side reactions, which had plagued earlier systems. The study outlines three fundamental cathode design strategies for future magnesium batteries:

Together, these strategies provide a clear roadmap for overcoming the historic limitations of magnesium-based systems. The researchers believe that RMBs could soon evolve into safe, fast-charging, and resource-resilient batteries for grid storage, electric vehicles, and beyond.

Original article: https://techxplore.com/news/2025-10-rechargeable-magnesium-battery-prototype-stable.html
DOI: 10.1038/s43246-025-00921-0


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