Revolutionizing Ethylene Production: A Breakthrough Catalyst Lowers CO₂ Conversion Energy

Posted by Quantum Server Networks • August 2025

Catalyst breakthrough for CO₂ to ethylene

As the global scientific community intensifies its efforts to decarbonize industrial processes, a team of researchers at the National University of Singapore (NUS) has unveiled a transformative development in sustainable chemistry. Led by Assistant Professor Lum Yanwei, the group has engineered a novel catalyst that enables the conversion of carbon dioxide (CO₂) into ethylene—a vital industrial compound—with dramatically reduced energy input.

Their research, recently published in Nature Synthesis, details how this innovation could mark a turning point in efforts to cut emissions from petrochemical manufacturing, one of the most CO₂-intensive sectors globally.

A Greener Route to Ethylene

Ethylene is a cornerstone of modern industry. It’s used to produce plastics, textiles, solvents, packaging, and many other essential products. Yet its conventional production method—steam cracking—relies on heating fossil fuels to extreme temperatures, emitting vast amounts of greenhouse gases.

By contrast, the new approach developed at NUS utilizes a specially engineered copper-based catalyst enhanced with trace amounts of cobalt dopants. These dopants, strategically placed just beneath the catalyst’s surface, shift the energetics of the CO₂-to-ethylene reaction. The result is a process that requires significantly less voltage and energy than previous electrochemical systems.

Inside the Science: Dopants and Efficiency

The breakthrough lies in precise atomic-level manipulation. "By making targeted changes, we were able to shift the most energy-demanding step in the reaction," explained Asst. Prof. Lum. This shift not only improves energy efficiency but also makes the system scalable for industrial application.

The team deployed their catalyst within a membrane electrode assembly (MEA)—a compact, multi-layered platform used in electrochemical reactors. The MEA enables efficient gas exchange and product separation, and is commonly found in cutting-edge fuel cell and carbon capture technologies.

In long-duration testing, the system achieved over 25% energy efficiency and demonstrated stability for more than 140 hours of continuous operation. It also successfully processed low-purity CO₂, such as that found in industrial flue gas—another key advantage for real-world deployment.

From Fundamental Insights to Practical Solutions

This innovation builds on the team’s earlier studies on hydrogen behavior in electrochemical CO₂ reduction. That fundamental research uncovered critical rate-limiting steps that informed the catalyst’s design. By addressing those bottlenecks, the new material represents a major leap forward.

Even more compelling, a cost analysis suggests that—if powered by affordable renewable electricity—this process could match the cost of traditional fossil-based ethylene production. The implications for industrial decarbonization are profound.

A Roadmap to Net-Zero Chemistry

As nations work toward their climate goals, materials and catalyst innovations like this are becoming increasingly crucial. Not only do they reduce carbon footprints, but they also lay the foundation for a circular carbon economy, where greenhouse gases are treated as feedstocks rather than waste.

The NUS catalyst is a compelling example of how combining nanoscience, electrochemistry, and materials engineering can lead to practical solutions with massive global impact.

Read the full article here: https://phys.org/news/2025-07-catalyst-lowers-energy-ethylene.html


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